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ZnFe2O4/BiVO4 Z-scheme heterojunction for efficient visible-light photocatalytic

《化学科学与工程前沿(英文)》 2023年 第17卷 第11期   页码 1728-1740 doi: 10.1007/s11705-023-2322-z

摘要: A novel Z-scheme ZnFe2O4/BiVO4 heterojunction photocatalyst was successfully synthesized using a convenient solvothermal method and applied in the visible light photocatalytic degradation of ciprofloxacin, which is a typical antibiotic contaminant in wastewater. The heterostructure of as-synthesized catalysts was confirmed using X-ray diffraction, scanning electron microscopy, transmission electron microscopy and X-ray photoelectron spectroscopy characterizations. Compared with the single-phase counterparts, ZnFe2O4/BiVO4 demonstrated considerably enhanced photogenerated charge separation efficiencies because of the Z-scheme transfer mechanism of electrons between the composite photocatalysts. Consequently, the 30% ZnFe2O4/BiVO4 catalyst afforded a degradation rate of up to 97% of 20 mg/L ciprofloxacin under 30 min of visible light irradiation with a total organic carbon removal rate of 50%, which is an excellent activity compared with ever reported BiVO4-based catalysts. In addition, the liquid chromatography-mass spectrometry and quantitative structure-activity relationships model analyses demonstrated that the toxicity of the intermediates was lower than that of the parent ciprofloxacin. Moreover, the as-synthesized ZnFe2O4/BiVO4 heterojunctions were quite stable and could be reused at least four times. This study thus provides a promising Z-scheme heterojunction photocatalyst for the efficient removal and detoxication of antibiotic pollutants from wastewater.

关键词: ZnFe2O4/BiVO4     Z-scheme heterojunction     photocatalytic degradation     ciprofloxacin    

Z-scheme CdS/WO on a carbon cloth enabling effective hydrogen evolution

《能源前沿(英文)》 2021年 第15卷 第3期   页码 678-686 doi: 10.1007/s11708-021-0768-6

摘要: Photocatalytic water splitting for hydrogen (H2) generation is a potential strategy to solve the problem of energy crisis and environmental deterioration. However, powder-like photocatalysts are difficult to recycle, and the agglomeration of particles would affect the photocatalytic activity. Herein, a direct Z-scheme CdS/WO3 composite photocatalyst was fabricated based on carbon cloth through a two-step process. With the support of carbon cloth, photocatalysts tend to grow uniformly for further applications. The experimental results showed that the H2 yield of adding one piece of CdS/WO3 composite material was 17.28 μmol/h, which was 5.5 times as compared to that of pure CdS-loaded carbon cloth material. A cycle experiment was conducted to verify the stability of the as-prepared material and the result demonstrated that the H2 generation performance of CdS/WO3 decreased slightly after 3 cycles. This work provides new ideas for the development of recyclable photocatalysts and has a positive significance for practical applications.

关键词: photocatalysis     CdS/WO3     carbon cloth     Z-scheme     hydrogen evolution    

Utilizing transparent and conductive SnO

Jing Gu, Hongtao Yu, Xie Quan, Shuo Chen, Junfeng Niu

《环境科学与工程前沿(英文)》 2020年 第14卷 第4期 doi: 10.1007/s11783-020-1251-z

摘要: Abstract • A novel Z-scheme Si-SnO2-TiOx with SnO2 as electron mediator is first constructed. • Transparent and conductive SnO2 can pass light through and promote charge transport. • VO from SnO2 and TiOx improve photoelectrochemical performances. • Efficient photocatalytic degradations originate from the Z scheme construction. Z-scheme photocatalysts, with strong redox ability, have a great potential for pollutants degradation. However, it is challenging to construct efficient Z-scheme photocatalysts because of their poor interfacial charge separation. Herein, by employing transparent and conductive SnO2 as electron mediator to pass light through and promote interfacial charge transportation, a novel Z-scheme photocatalyst Si-SnO2-TiOx (1

关键词: Z-scheme photocatalyst     Tin oxide     Electron mediator     Organic pollutant    

Influence of using amorphous silicon stack as front heterojunction structure on performance of interdigitatedback contact-heterojunction solar cell (IBC-HJ)

Rui JIA,Ke TAO,Qiang LI,Xiaowan DAI,Hengchao SUN,Yun SUN,Zhi JIN,Xinyu LIU

《能源前沿(英文)》 2017年 第11卷 第1期   页码 96-104 doi: 10.1007/s11708-016-0434-6

摘要: Interdigitated back contact-heterojunction (IBC-HJ) solar cells can have a conversion efficiency of over 25%. However, the front surface passivation and structure have a great influence on the properties of the IBC-HJ solar cell. In this paper, detailed numerical simulations have been performed to investigate the potential of front surface field (FSF) offered by stack of n-type doped and intrinsic amorphous silicon (a-Si) layers on the front surface of IBC-HJ solar cells. Simulations results clearly indicate that the electric field of FSF should be strong enough to repel minority carries and cumulate major carriers near the front surface. However, the over-strong electric field tends to drive electrons into a-Si layer, leading to severe recombination loss. The n-type doped amorphous silicon (n-a-Si) layer has been optimized in terms of doping level and thickness. The optimized intrinsic amorphous silicon (i-a-Si) layer should be as thin as possible with an energy band gap ( ) larger than 1.4 eV. In addition, the simulations concerning interface defects strongly suggest that FSF is essential when the front surface is not passivated perfectly. Without FSF, the IBC-HJ solar cells may become more sensitive to interface defect density.

关键词: amorphous silicon     front surface field     simulations     interdigitated back contact-heterojunction solar cells    

Z源逆变器在异步电动机中的应用

朱红,祝龙记,夏若飞

《中国工程科学》 2014年 第16卷 第3期   页码 86-91

摘要: 本文采用IFOC技术来控制异步电机的速度大小,并使用Z源逆变器,即在逆变器主电路前加上一对阻抗(LC)网络,通过控制直通占空比,可以实现升/降压功能、提高异步电机的效率。

关键词: IFOC     异步电机     Z源逆变器    

Exergy analysis of R1234ze(Z) as high temperature heat pump working fluid with multi-stage compression

WANG, R.Z. WANG

《能源前沿(英文)》 2017年 第11卷 第4期   页码 493-502 doi: 10.1007/s11708-017-0510-6

摘要: In this paper, the simulation approach and exergy analysis of multi-stage compression high temperature heat pump (HTHP) systems with R1234ze(Z) working fluid are conducted. Both the single-stage and multi-stage compression cycles are analyzed to compare the system performance with 120°C pressurized hot water supply based upon waste heat recovery. The exergy destruction ratios of each component for different stage compression systems are compared. The results show that the exergy loss ratios of the compressor are bigger than that of the evaporator and the condenser for the single-stage compression system. The multi-stage compression system has better energy and exergy efficiencies with the increase of compression stage number. Compared with the single-stage compression system, the coefficient of performance (COP) improvements of the two-stage and three-stage compression system are 9.1% and 14.6%, respectively. When the waste heat source temperature is 60°C, the exergy efficiencies increase about 6.9% and 11.8% for the two-stage and three-stage compression system respectively.

关键词: multi-stage compression     high temperature heat pump     heat recovery     exergy destruction     R1234ze(Z) working fluid    

基于Z数的TODIM与TOPSIS方法 None

Renato A. KROHLING, André G. C. PACHECO, Guilherme A. dos SANTOS

《信息与电子工程前沿(英文)》 2019年 第20卷 第2期   页码 283-291 doi: 10.1631/FITEE.1700434

摘要: 提出一种针对多标准决策问题处理Z数的方法。使用模糊数A和B的有序对Z=(A, B)定义Z数,其中A是兴趣变量的语言值,B是A的概率测度语言值。将Z数转化为模糊数,Z-TODIM和Z-TOPSIS分别是模糊TODIM和模糊TOPSIS的直接扩展。将提出的方法应用于两个案例并与使用精确数的标准方法比较,结果证明其可行。

关键词: 多标准决策;TODIM;TOPSIS;模糊数;Z   

Z-箍缩——有前景的聚变能源新途径

彭先觉,华欣生

《中国工程科学》 2008年 第10卷 第1期   页码 47-53

摘要:

简要介绍了快Z-箍缩的基本概念;综述了快Z-箍缩等离子体研究及其作为高能密度物理与惯性约束聚变(ICF),尤其作为低成本聚变能源研究的最新进展;探讨了快Z-箍缩驱动ICF作为聚变能源可能遇到的技术问题及应用前景。

关键词: Z-箍缩内爆     高能密度物理     惯性约束聚变     聚变能源    

Z干扰信道下非正则信号的最佳设计策略 Article

Dan LI, Shan WANG, Fang-lin GU

《信息与电子工程前沿(英文)》 2017年 第18卷 第11期   页码 1900-1912 doi: 10.1631/FITEE.1700030

摘要: 本文提出一种用于在干扰被视为加性高斯噪声的假设下在Z干扰信道(z-interference channel, Z-IC)上实现非正则高斯信号(IGS)的Pareto边界(可实现速率区域的边界)。

关键词: Z干扰信道;非正则信号;和速率;帕累托边界;协方差;伪协方差    

Plasma enhanced chemical vapor deposition of excellent a-Si:H passivation layers for a-Si:H/c-Si heterojunction

Lei ZHAO,Wenbin ZHANG,Jingwei CHEN,Hongwei DIAO,Qi WANG,Wenjing WANG

《能源前沿(英文)》 2017年 第11卷 第1期   页码 85-91 doi: 10.1007/s11708-016-0437-3

摘要: The intrinsic a-Si:H passivation layer inserted between the doped a-Si:H layer and the c-Si substrate is very crucial for improving the performance of the a-Si:H/c-Si heterojunction (SHJ) solar cell. The passivation performance of the a-Si:H layer is strongly dependent on its microstructure. Usually, the compact a-Si:H deposited near the transition from the amorphous phase to the nanocrystalline phase by plasma enhanced chemical vapor deposition (PECVD) can provide excellent passivation. However, at the low deposition pressure and low deposition power, such an a-Si:H layer can be only prepared in a narrow region. The deposition condition must be controlled very carefully. In this paper, intrinsic a-Si:H layers were prepared on n-type Cz c-Si substrates by 27.12 MHz PECVD at a high deposition pressure and high deposition power. The corresponding passivation performance on c-Si was investigated by minority carrier lifetime measurement. It was found that an excellent a-Si:H passivation layer could be obtained in a very wide deposition pressure and power region. Such wide process window would be very beneficial for improving the uniformity and the yield for the solar cell fabrication. The a-Si:H layer microstructure was further investigated by Raman and Fourier transform infrared (FTIR) spectroscopy characterization. The correlation between the microstructure and the passivation performance was revealed. According to the above findings, the a-Si:H passivation performance was optimized more elaborately. Finally, a large-area SHJ solar cell with an efficiency of 22.25% was fabricated on the commercial 156 mm pseudo-square n-type Cz c-Si substrate with the open-circuit voltage ( ) of up to 0.732 V.

关键词: PECVD     high pressure and high power     a-Si:H microstructure     passivation     heterojunction solar cell    

Analysis of the double-layer α-Si:H emitter with different doping concentrations for α-Si:H/c-Si heterojunction

Haibin HUANG,Gangyu TIAN,Tao WANG,Chao GAO,Jiren YUAN,Zhihao YUE,Lang ZHOU

《能源前沿(英文)》 2017年 第11卷 第1期   页码 92-95 doi: 10.1007/s11708-016-0432-8

摘要: Double-layer emitters with different doping concentrations (DLE) have been designed and prepared for amorphous silicon/crystalline silicon (α-Si:H/c-Si) heterojunction solar cells. Compared with the traditional single layer emitter, both the experiment and the simulation (AFORS-HET, http://www.paper.edu.cn/html/releasepaper/2014/04/282/) prove that the double-layer emitter increases the short circuit current of the cells significantly. Based on the quantum efficiency (QE) results and the current-voltage-temperature analysis, the mechanism for the experimental results above has been investigated. The possible reasons for the increased current include the enhancement of the QE in the short wavelength range, the increase of the tunneling probability of the current transport and the decrease of the activation energy of the emitter layers.

关键词: double-layer emitter     α-Si:H/c-Si heterojunction solar cell     short circuit current     quantum efficiency     current-voltage-temperature    

Fire hazard in transportation infrastructure: Review, assessment, and mitigation strategies

Z. NASER

《结构与土木工程前沿(英文)》 2021年 第15卷 第1期   页码 46-60 doi: 10.1007/s11709-020-0676-6

摘要: This paper reviews the fire problem in critical transportation infrastructures such as bridges and tunnels. The magnitude of the fire problem is illustrated, and the recent increase in fire problems in bridges and tunnels is highlighted. Recent research undertaken to address fire problems in transportation structures is reviewed, as well as critical factors governing the performance of those structures. Furthermore, key strategies recommended for mitigating fire hazards in bridges and tunnels are presented, and their applicability to practical situations is demonstrated through a practical case study. Furthermore, research needs and emerging trends for enhancing the “state-of-the-art” in this area are discussed.

关键词: fire hazard     bridges     tunnels     fire resistance     mitigation strategies     transportation infrastructure    

硅微z轴谐振陀螺仪负电刚度效应分析及实验验证

夏敦柱,周百令,王寿荣

《中国工程科学》 2007年 第9卷 第8期   页码 66-68

摘要:

介绍了在开环工作状态下硅微z轴谐振陀螺仪由于加工工艺缺陷所导致的误差机理。通过对硅微z轴陀螺仪敏感模态的反馈力与谐振频率的关系分析,间接得出了在敏感方向上电负刚度与力矩器所施电压的内在联系,并在实验上进一步验证电刚度效应。这将为下一步闭环控制方案的设计奠定重要基础。

关键词: 硅微z轴陀螺仪     负电刚度     力矩反馈器     微机电系统    

直接驱动Z箍缩的FLTD型脉冲功率源的发展

孙凤举,邱爱慈,曾正中,曾江涛,丛培天

《中国工程科学》 2009年 第11卷 第11期   页码 56-63

摘要:

介绍了快直线型变压器(FLTD)脉冲源的技术特点;概述了美国圣地亚国家实验室与俄罗斯强流电子学研究所合作研制的FLTD-Z模块的新进展,基于FLTD拟重复频率运行的针对聚变能源(IFE)应用的原理性样机Z-POP装置,以及下一代惯性约束核聚变(ICF)和IFE用的指标为6 MV,60 MA/90 MA和100 ns FLTD型直接驱动脉冲源的概念设想

关键词: Z箍缩     直接驱动     FLTD型脉冲加速器     高功率脉冲加速器     概念设计    

Fluorene-based narrow-band-gap copolymers for red light-emitting diodes and bulk heterojunction photovoltaic

SUN Mingliang, WANG Li, XIA Yangjun, DU Bin, LIU Ransheng, CAO Yong

《化学科学与工程前沿(英文)》 2008年 第2卷 第3期   页码 257-264 doi: 10.1007/s11705-008-0052-x

摘要: A series of narrow band-gap conjugated copolymers (PFO-DDQ) derived from 9,9-dioctylfluorene (DOF) and 2,3-dimethyl-5,8-dithien-2-yl-quinoxalines (DDQ) is prepared by the palladium-catalyzed Suzuki coupling reaction with the molar feed ratio of DDQ at around 1%, 5%, 15%, 30% and 50%, respectively. The obtained polymers are readily soluble in common organic solvents. The solutions and the thin solid films of the copolymers absorb light from 300–590 nm with two absorbance peaks at around 380 and 490 nm. The intensity of 490 nm peak increases with the increasing DDQ content in the polymers. Efficient energy transfer due to exciton trapping on narrow-band-gap DDQ sites has been observed. The PL emission consists exclusively of DDQ unit emission at around 591–643 nm depending on the DDQ content in solid film. The EL emission peaks are red-shifted from 580 nm for PFO-DDQ1 to 635 nm for PFO-DDQ50. The highest external quantum efficiency achieved with the device configuration ITO/PEDOT/PVK/PFO-DDQ15/Ba/Al is 1.33% with a luminous efficiency 1.54 cd/A. Bulk heterojunction photovoltaic cells fabricated from composite films of PFO-DDQ30 copolymer and [6,6]-phenyl C butyric acid methyl ester (PCBM) as electron donor and electron acceptor, respectively in device configuration: ITO/PEDOT:PSS/PFO-DDQ30:PCBM/PFPNBr/Al shows power conversion efficiencies of 1.18% with open-circuit voltage () of 0.90 V and short-circuit current density () of 2.66 mA/cm under an AM1.5 solar simulator (100 mW/cm). The photocurrent response wavelengths of the PVCs based on PFO-DDQ30/PCBM blends covers 300–700 nm. This indicates that these kinds of low band-gap polymers are promising candidates for polymeric solar cells and red light-emitting diodes.

关键词: simulator     Efficient     band-gap     PFO-DDQ50     intensity    

标题 作者 时间 类型 操作

ZnFe2O4/BiVO4 Z-scheme heterojunction for efficient visible-light photocatalytic

期刊论文

Z-scheme CdS/WO on a carbon cloth enabling effective hydrogen evolution

期刊论文

Utilizing transparent and conductive SnO

Jing Gu, Hongtao Yu, Xie Quan, Shuo Chen, Junfeng Niu

期刊论文

Influence of using amorphous silicon stack as front heterojunction structure on performance of interdigitatedback contact-heterojunction solar cell (IBC-HJ)

Rui JIA,Ke TAO,Qiang LI,Xiaowan DAI,Hengchao SUN,Yun SUN,Zhi JIN,Xinyu LIU

期刊论文

Z源逆变器在异步电动机中的应用

朱红,祝龙记,夏若飞

期刊论文

Exergy analysis of R1234ze(Z) as high temperature heat pump working fluid with multi-stage compression

WANG, R.Z. WANG

期刊论文

基于Z数的TODIM与TOPSIS方法

Renato A. KROHLING, André G. C. PACHECO, Guilherme A. dos SANTOS

期刊论文

Z-箍缩——有前景的聚变能源新途径

彭先觉,华欣生

期刊论文

Z干扰信道下非正则信号的最佳设计策略

Dan LI, Shan WANG, Fang-lin GU

期刊论文

Plasma enhanced chemical vapor deposition of excellent a-Si:H passivation layers for a-Si:H/c-Si heterojunction

Lei ZHAO,Wenbin ZHANG,Jingwei CHEN,Hongwei DIAO,Qi WANG,Wenjing WANG

期刊论文

Analysis of the double-layer α-Si:H emitter with different doping concentrations for α-Si:H/c-Si heterojunction

Haibin HUANG,Gangyu TIAN,Tao WANG,Chao GAO,Jiren YUAN,Zhihao YUE,Lang ZHOU

期刊论文

Fire hazard in transportation infrastructure: Review, assessment, and mitigation strategies

Z. NASER

期刊论文

硅微z轴谐振陀螺仪负电刚度效应分析及实验验证

夏敦柱,周百令,王寿荣

期刊论文

直接驱动Z箍缩的FLTD型脉冲功率源的发展

孙凤举,邱爱慈,曾正中,曾江涛,丛培天

期刊论文

Fluorene-based narrow-band-gap copolymers for red light-emitting diodes and bulk heterojunction photovoltaic

SUN Mingliang, WANG Li, XIA Yangjun, DU Bin, LIU Ransheng, CAO Yong

期刊论文